Benzoxazole-Directed Halogen Dance of Bromofuran
نویسندگان
چکیده
منابع مشابه
Induction The dance of shadows
Statistics stems out from induction. Induction is a long lasting notion in philosophy. The nature of notions in philosophy are such that neither they can be solved completely nor one can leave them forever. One of the most important problem in induction is “the problem of induction”. In this paper we give a short history of induction and discuss some aspects of the problem of induction.
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Since the discovery of the halogen dance (HD) reaction more than 60 years ago, numerous insights into the mechanism have been unveiled. To date however, the reaction has not been investigated from a theoretical perspective. Density functional theory (DFT) was used to model the potential energy surface linking the starting reagents to the lithiated products for each step in the mechanism using a...
متن کاملModeling a Halogen Dance (HD) Reaction Mechanism: A Density Functional Theory (DFT) Study
© 2016 Wiley Periodicals, Inc. This is the peer reviewed version of the following article: Jones, L and Whitaker, BJ (2016) Modeling a halogen dance reaction mechanism: A density functional theory study. Journal of Computational Chemistry, 37 (18). pp. 1697-1703, which has been published in final form at http://dx.doi.org/10.1002/jcc.24385. This article may be used for non-commercial purposes i...
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The interactions between the two CX3 groups in perhalogenated ethanes, X3C–CX3 are studied, with X3C–CX3 = H3C–CH3, F3C–CF3, F3C–CCl3, and Cl3C–CCl3. Utilising the recently developed method for revealing non-covalent interactions in molecular systems by Johnson et al. [1], a previously overlooked non-covalent interaction between halogens attached to opposite carbon atoms is unearthed. Further i...
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ژورنال
عنوان ژورنال: Synlett
سال: 2017
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-0036-1588142